Wilcannia Airport in north-western NSW has already hit 46.3 degrees Celsius today with a forecast top of 48C.
At noon, Fowlers Gap and White Cliffs Airport were not far behind, recording temperatures over 45C.
Wentworth is expected to reach 49 while Ivanhoe is also forecast to reach 48C.
Trangie Research Station along with Dubbo and Mudgee airports broke January records yesterday.
In Trangie, temperatures reached 47.3C for the first time in January in the 58 years since data has been collected at the location.
Meanwhile, Dubbo reached January records of 46.1C and Mudgee 42.9C.
Bureau of Meteorology senior forecaster Chrisie Johnson said overnight temperatures offered little relief for some places in the far west.
"Broken Hill stayed just around 30 degrees overnight and Tibooburra did not even get below 31," Ms Johnson said
"We're looking at another hot one today.
"The peak of the heat is going to be migrating back out into the far west."